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621.
The imprint of orbital cycles, which result from the varying eccentricity of the Earth’s orbit and changes in the orientation of its axis, have been recognised throughout the Phanerozoic rock record. Variations in insolation and their effect on climate are generally considered to be the sole transfer mechanism between the orbital variables and cyclic sedimentary successions. Common oceanographic principles, however, show that the ocean tide also responds to variations in the orbital parameters. The ocean tide has not yet been considered to be a valid, additional transfer mechanism for the orbital variations. In geological studies of Milankovitch cycles in sedimentary successions the insolation paradigm offers satisfying explanations, and the role of long‐term variations of the ocean tide has not yet been appreciated. Variations in the ocean tide, related to changing eccentricity (at present 0·0165, theoretical maximum 0·0728), affect a variety of oceanographic and sedimentary processes. In addition to the widely accepted paradigm of orbitally forced insolation changes, the tidal transfer of orbital signals may explain certain less well‐understood aspects of orbitally induced cycles in the stratigraphic record related to ocean mixing, organic productivity, and tidal processes in shallow seas and deep water. Variations of the ocean tide in relation to the 18·6 year lunar nodal cycle, which has no insolation counterpart by which they may be obscured, indeed show that these relatively small variations can produce significant effects in sedimentary environments that are sensitive to variations in the strength of the ocean tide. In analogy with the 18·6 year lunar nodal cycle, orbital variations of the tide on Milankovitch time scales are likely to have affected sedimentary systems in the past.  相似文献   
622.
623.
Observations of the large two-ribbon flare on 7 November 2004 made using SOHO and TRACE data are interpreted in terms of a three-dimensional magnetic field model. Photospheric flux evolution indicates that ?1.4×1043 Mx2 of magnetic helicity was injected into the active region during the 40-hour buildup prior to the flare. The magnetic model places a lower bound of 8×1031 ergs on the energy stored by this motion. It predicts that 5×1021 Mx of flux would need to be reconnected during the flare to release the stored energy. This total reconnection compares favorably with the flux swept up by the flare ribbons, which we measure using high-time-cadence TRACE images in 1?600 Å. Reconnection in the model must occur in a specific sequence that would produce a twisted flux rope containing significantly less flux and helicity (1021 Mx and ?3×1042 Mx2, respectively) than the active region as a whole. The predicted flux compares favorably with values inferred from the magnetic cloud observed by Wind. This combined analysis yields the first quantitative picture of the flux processed through a two-ribbon flare and coronal mass ejection.  相似文献   
624.
We have investigated the thermodynamics of mixing between aragonite (orthorhombic CaCO3) and strontianite (SrCO3). In agreement with experiment, our simulations predict that there is a miscibility gap between the two solids at ambient conditions. All SrxCa1−xCO3 solids with compositions 0.12 < x < 0.87 are metastable with respect to separation into a Ca-rich and a Sr-rich phase. The concentration of Sr in coral aragonites (x ∼ 0.01) lies in the miscibility region of the phase diagram, and therefore formation of separated Sr-rich phases in coral aragonites is not thermodynamically favorable. The miscibility gap disappears at around 380 K. The enthalpy of mixing, which is positive and nearly symmetric with respect to x = 0.5, is the dominant contribution to the excess free energy, while the vibrational and configurational entropic contributions are small and of opposite sign. We provide a detailed comparison of our simulation results with available experimental data.  相似文献   
625.
Eighteen sediment samples and six water-column samples were collected in a small (6 km2), coastal embayment (Port Jefferson Harbor, New York) to define a high-resolution spatial distribution of metals and to elucidate sources of contaminants to the harbor. Sediment metal (Ag, Cu, Fe, Ni, Pb, V, and Zn) concentrations varied widely, reflecting differences in sediment grain size, with higher metal concentrations located in the fine-grained inner harbor sediments. Calculated enrichment factors for these sediments show that Ag, Pb, Cu, and Zn are elevated relative to both crustal abundances and their respective abundances in sediments in central Long Island Sound. Metal concentrations were 1.2 to 10 fold greater in water from the inner harbor compared to water from Long Island Sound collected outside the mouth of the harbor. Spatial variations in trace metals in surface waters within the bay parallel the spatial variations of trace metals in sediments within the harbor. Elevated water-column metal concentrations appear to be partially derived from a combination of diagenetic remobilization from contaminated sediments (e.g., Ag) and anthropogenic sources (e.g., Cu and Zn) within the southern portions of the harbor. Although the National Status and Trends Program had reported previously that sediment metal concentrations in Port Jefferson Harbor were low, the results of this study show sediment metals have high spatial variability and are enriched in the inner harbor sediments at levels comparable to more urbanized western north shore Long Island harbors.  相似文献   
626.
The Abbott Unit (∼508 Ma) and the Vegetation Unit (∼475 Ma) of the Terra Nova Intrusive Complex (northern Victoria Land, Antarctica) represent the latest magmatic events related to the Early Paleozoic Ross Orogeny. They show different emplacement styles and depths, ranging from forcible at 0.4–0.5 GPa for the Abbott Unit to passive at ∼0.2 GPa for the Vegetation Unit. Both units consist of mafic, felsic and intermediate facies which collectively define continuous chemical trends. The most mafic rocks from both units show different enrichment in trace element and Sr-Nd isotopic signatures. Once the possible effects of upper crustal assimilation-fractional crystallisation (AFC) and lower crustal coupled AFC and magma refilling processes have been taken into account the following features are recognised: (1) the modelled primary Abbott Unit magma shows a slightly enriched incompatible element distribution, similar to common continental arc basalts and (2) the modelled primary Vegetation Unit magma displays highly enriched isotope ratios and incompatible element patterns. We interpreted these major changes in magmatic affinity and emplacement style as linked to a major change in the tectonic setting affecting melt generation, rise and emplacement of the magmas. The Abbott Unit mafic melts were derived from a mantle wedge above a subduction zone, with subcontinental lithospheric mantle marginally involved in the melting column. The Vegetation Unit mafic melts are regarded as products of a different source involving an old layer of subcontinental lithospheric mantle. The crustal evolution of both types of mafic melts is marked by significant compositional contrasts in Sr and Nd isotopes between mafic and associated felsic rocks. The crustal isotope signature showed an increase with felsic character. Geochemical variations for both units can be accounted for by a similar two-stage hybridisation process. In the first stage, the most mafic magma evolved mainly by fractional crystallisation coupled with assimilation of metasedimentary rocks having crustal time-integrated Sr and Nd compositions similar to those of locally exposed metamorphic basement. The second stage involves contaminated products mixing with independently generated crustal melts. Petrographic, geochemical and isotope data also provide evidence of significant compositional differences in the felsic end-members, pointing to the involvement of metaigneous and metasedimentary source rocks for the Abbott granite and Vegetation leucogranite, respectively. Received: 31 March 1998 / Accepted: 3 May 1999  相似文献   
627.
The paper presents two algorithms for the computation of intersection of geodesics and minimum distance from a point to a geodesic on the ellipsoid, respectively. They are based on the iterative use of direct and inverse problems of geodesy by means of their implementations with machine-precision accuracy in GeographicLib. The algorithms yield the same results as those obtained by Karney’s approach based on the use of auxiliary ellipsoidal gnomonic projections, with the advantage on our side that the algorithms are not limited to distances below 10000 km. This results in our algorithm being the only general solution for the problem of minimum distance from a point to a geodesic on the ellipsoid.  相似文献   
628.
Air temperature feedback results from the thermal-radiative coupling between the atmosphere and the surface and plays an important role in surface energy balance. This paper reveals the contribution of air temperature feedback to the global warming from 1980 to 2000. The air temperature feedback kernel, evaluated using the ERA-Interim reanalysis data, is used to discuss the physical mechanism for air temperature feedback, the dependency of the strength of air temperature feedback on the climatological spatial distributions of air temperature, water vapor and cloud content, and the contributions of air temperature feedback to rapid global warming. The coupling between temperature feedback and each of the external forcings and individual feedback processes will amplify the anomaly of direct energy flux convergence at the surface induced by the external forcings and individual processes. The air temperature feedback amplifies the initial surface warming due to the increase in CO2 concentration, ice and snow melting, increase in water vapor, and change in ocean heat storage. It also amplifies the surface warming due to the longwave radiaitve forcing associated with the increase in cloud cover, which acts to suppress the cooling of the shortwave effect of cloud forcing. Overall, temperature feedback plays an important role in the global warming from 1980 to 2000, as the net positive contribution to the perturbation of global mean energy flux at the surface from the air temperature feedback is larger than the net negative contribution from external forcing and all non-temperature feedbacks.  相似文献   
629.
Hyphal penetration, mineral dissolution and neoformation at the lichen–rock interface have been widely characterized by microscopic and spectroscopic studies, and considered as proxies of lichen deterioration of stone substrates. However, these phenomena have not been clearly related to experimental data on physical properties related to stone durability, and the physical consequences of lichen removal from stone surfaces have also been overlooked. In this study, we combine microscopic and spectroscopic characterization of the structural organization of epi‐ and endolithic lichens (Caloplaca marina (Wedd.) Du Rietz, Caloplaca ochracea (Schaer.) Flagey, Bagliettoa baldensis (A.Massal.) Vězda, Porina linearis (Leight.) Zahlbr., Verrucaria nigrescens Pers.) at the interface with limestones of interest for Cultural Heritage (Portland Limestone, Botticino Limestone), with analysis of rock properties (water absorption, surface hardness) relevant for durability, before and after the removal or scraping of lichen thalli. Observations using reflected‐light and electron microscopy, and Raman analyses, showed lichen–limestone stratified interfaces, differing in the presence/absence and depth of lichen anatomical layers (lithocortex, photobiont layer, pervasive and sparse hyphal penetration component) depending on species and lithology. Specific structural organizations of lichen–rock interface were found to be associated with differential patterns of water absorption increase, evaluated by Karsten tube, in comparison with surfaces with microbial biofilms only, even more pronounced after the removal or scraping of the upper structural layers. Equotip measurements on surfaces bearing intact thalli showed lower hardness in comparison with control surfaces. By contrast, after the removal or scraping procedures, Equotip values were similar to or higher than those of controls, suggesting that the increasing open porosity may be related to a biogenic hardening process. Such counterposed patterns of porosity increase and hardening need to be considered when models relating lichen occurrence on limestones and biogeomorphological surface evolution are proposed, and to evaluate the consequences of lichen removal from stone‐built cultural heritage. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
630.
In this paper sediment yield data, measured from 1978 to 1994 in two small Calabrian basins (W2 and W3) reafforested with eucalyptus trees (Eucalyptus occidentalis Engl.), and the Modified Universal Soil Loss Equation (MUSLE) applied in a distributed form are used to evaluate the anti-erosive effects of eucalyptus cover. At first step the sediment yield measurements observed in W2 basin are used to estimate a single cover management factor representative of the eucalyptus coppice and equal to the median value (0·164) of the cover management factor values calculated for each runoff event. Then, the reliability of the selected representative cover management factor is verified on W3 by comparing the cumulative distribution function (CDF) of the measured sediment yield with the CDF of the calculated one. Finally, the temporal analysis of the crop and management factor is developed searching, at monthly and annual scale, the correlation between crop anti-erosive effectiveness and rainfall erosivity index. © 1998 John Wiley & Sons, Ltd.  相似文献   
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